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>印染行業(yè)廢水處理基本工藝</span></dt> <dd> <div id="o0u82yaiea" class="View"> <div id="o0u82yaiea" class="PageView"> <h1 id="inside_rnewtil">印染行業(yè)廢水處理基本工藝</h1> <div id="o0u82yaiea" class="inside_rnewtime">更新更新時間：2021-10-21 點擊次數(shù)：3053次</div> <div id="o0u82yaiea" class="inside_rnewcon"><p><span style="color: rgb(0, 102, 0); background-color: rgb(255, 255, 255); font-family: 宋體, SimSun;"> 印染行業(yè)廢水處理基本工藝生物吸附段對有機物的去除，主要是靠污泥絮體的吸附作用，生物降解只占三分之一左右，由于物理化學(xué)作用占主導(dǎo)作用因此吸附段對毒物值負荷以及溫度的變化都有較強的適應(yīng)性。</span></p><p><span style="color: rgb(0, 102, 0); background-color: rgb(255, 255, 255); font-family: 宋體, SimSun;"></span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">我國日排放印染廢水量為(300～400)×104t，是各行業(yè)中的排污大戶之一。印染廢水主要由退漿廢水、煮煉廢水、漂白廢水、絲光廢水、染色廢水和印花廢水組成，印染加工的四個工序都要排出廢水，預(yù)處理階段(包括退漿、煮煉、漂白、絲光等工序)要排出退漿廢水、煮煉廢水、漂白廢水和絲光廢水，染色工序排出染色廢水，印花工序排出印花廢水和皂液廢水，整理工序則排出整理廢水。通常所說的印染廢水是以上各類廢水的混合廢水，或除漂白廢水以外的綜合廢水。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> </span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">印染廢水的水質(zhì)隨采用的纖維種類和加工工藝的不同而異，污染物組分差異很大。印染廢水一般具有污染物濃度高、種類多、含有毒有害成分及色度高等特點。一般印染廢水pH值為6~10， CODCr為400~1000mg/L，BOD5為100~400mg/L， SS為100~200mg/L，色度為100~400倍。但當印染工藝、采用的纖維種類和加工工藝變化后，廢水水質(zhì)將有較大變化。近年來由于化學(xué)纖維織物的發(fā)展，仿真絲的興起和印染后整理技術(shù)的進步，使PVA漿料、人造絲堿解物(主要是鄰苯二甲酸類物質(zhì))、新型助劑等難生化降解有機物大量進入印染廢水，其CODCr濃度也由原來的數(shù)百mg/L上升到2000~3000mg/L以上， BOD5增大到800mg/L以上， pH值達11.5 ~12，從而使原有的生物處理系統(tǒng)CODCr去除率從70%下降到50%左右，甚至更低。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> </span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;"> 隨著人們對環(huán)境質(zhì)量要求越來越高，印染廢水排放標準也越來越嚴，對于高、中難度處理印染廢水，單獨的生化或物化處理都難以達到排放要求。目前國內(nèi)的印染廢水處理多采用以生化法為主，物理化學(xué)法為輔的手段。但是由于近年來化纖織物的發(fā)展和印染后整理技術(shù)的進步，尤其是PVA漿料、新型助劑等難生化降解有機物大量進入印染廢水，給印染廢水的處理增加了難度。普通的生物處理系統(tǒng)大都由于處理效率低下而使出水的CODcr、色度等污染指標達不到排放要求。此外，PVA等化學(xué)漿料造成的CODcr占印染廢水總CODcr的比例相當大，但由于很難被普通微生物所利用而使其去除率只有20~30%。針對上述問題，近年來國內(nèi)外都開展了一些研究工作，主要是新的生物處理工藝和高效專門細菌、以及新型化學(xué)藥劑的探索和應(yīng)用研究。其中具有代表性的有：厭氧—好氧生物處理工藝、高效脫色菌和PVA降解菌的篩選與應(yīng)用研究、高效脫色混凝劑的研制等。根據(jù)我們多年處理印染廢水實踐經(jīng)驗，總結(jié)提出：以“強化生物吸附+厭氧水解酸化+好氧生化處理"為主體的工藝是比較經(jīng)濟適用的印染廢水處理技術(shù)。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> </span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">1　生物吸附</span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;"> 一般把活性污泥作用分為三步：步，在活性污泥與廢水接觸的初期，通過附聚、吸附、吸收作用使水中有機物含量迅速降低：第二步，是活性污泥對有機物的氧化分解，用來使細菌生長，維持微生物的新陳代謝：第三步，沉淀分離。其中步是物理、化學(xué)、生物作用共同產(chǎn)生的結(jié)果，這一過程的綜合作用———附聚、吸附、吸收作用稱為生物吸附。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/><br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/>生物吸附的特點：</span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">1)生物吸附段中存活大量的細菌，而且還不斷地進行繁殖、適應(yīng)、淘汰、優(yōu)選等過程，從而能夠培育出適應(yīng)性和活性都很強的微生物群體，本工藝不設(shè)初沉池，使原廢水中的微生物全部進入系統(tǒng)，使吸附再生段成為一個開放式的生物動力學(xué)系統(tǒng)。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> </span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">2)生物吸附段負荷較高，有利于增殖速度快的微生物增長繁殖，而且在這里成活的只能是抗沖擊能力強的原核細菌，其它微生物都不能存活。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> </span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">3)廢水經(jīng)生物吸附段處理后，廢水的可生化性大大提高，有利于后續(xù)處理單元的工作。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> </span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">4)生物吸附段污泥產(chǎn)率較高，吸附能力強，重金屬、難降解物質(zhì)等等，都可以通過污泥的吸附作用，而得到去除。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> </span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">5)生物吸附段對有機物的去除，主要是靠污泥絮體的吸附作用，生物降解只占三分之一左右，由于物理化學(xué)作用占主導(dǎo)作用因此吸附段對毒物值負荷以及溫度的變化都有較強的適應(yīng)性。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/><br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> <br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/>2　強化生物吸附法預(yù)處理</span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">混凝沉淀與生物吸附兩種預(yù)處理方法均有效果，但因混凝沉淀的投藥量較大、工作量較大、操作復(fù)雜，而生物吸附的投藥量較少、處理效果較好，故根據(jù)印染廢水CODcr濃度較高， pH偏高的特點，我們提出強化生物吸附法即生物吸附結(jié)合混凝沉淀作為預(yù)處理手段。利用污泥絮體的強吸附作用，吸附廢水中的污染物質(zhì)和難降解物質(zhì)：同時補充一定量的混凝藥劑進行混凝反應(yīng)，反應(yīng)后的混合液進入吸附沉淀池進行沉淀分離。這樣，一方面可以減少混凝藥劑的投加量，降低運行費用：另一方面，可以減少處理工藝中污泥總量的產(chǎn)生量，減少處理費用。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> </span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">印染各工序的排水情況一般是：<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> <br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> (1)退漿廢水：水量較小，但污染物濃度高，其中含有各種漿料、漿料分解物、纖維屑、淀粉堿和各種助劑。廢水呈堿性， pH值為12左右。上漿以淀粉為主的(如棉布)退漿廢水，其COD、BOD值都很高，可生化性較好：上漿以聚乙烯醇(PVA)為主的(如滌棉經(jīng)紗)退漿廢水，COD高而BOD低，廢水可生化性較差。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> </span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">(2)煮煉廢水：水量大，污染物濃度高，其中含有纖維素、果酸、蠟質(zhì)、油脂、堿、表面活性劑、含氮化合物等，廢水呈強堿性，水溫高，呈褐色。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> </span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">(3)漂白廢水：水量大，但污染較輕，其中含有殘余的漂白劑、少量醋酸、草酸、硫代硫酸鈉等。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> </span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">(4)絲光廢水：含堿量高，NaOH含量在3% ~5%，多數(shù)印染廠通過蒸發(fā)濃縮回收NaOH，所以絲光廢水一般很少排出，經(jīng)過工藝多次重復(fù)使用最終排出的廢水仍呈強堿性，BOD、COD、SS均較高。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> </span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">(5)染色廢水：水量較大，水質(zhì)隨所用染料的不同而不同，其中含漿料、染料、助劑、表面活性劑等，一般呈強堿性，色度很高，COD較BOD高得多，可生化性較差。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> </span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">(6)印花廢水：水量較大，除印花過程的廢水外，還包括印花后的皂洗、水洗廢水，污染物濃度較高，其中含有漿料、染料、助劑等，BOD、COD均較高。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> </span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">(7)整理廢水：水量較小，其中含有纖維屑、樹脂、油劑、漿料等。<br data-filtered="filtered" style="clear: both; width: 0px; height: 0px;"/> </span></p><p style="margin-top: 10px; margin-bottom: 10px; padding: 0px; color: rgb(51, 51, 51); background-color: rgb(248, 248, 248); text-indent: 28px; font-family: 宋體; white-space: normal;"><span style="font-family: 宋體, SimSun;">(8)堿減量廢水：是滌綸仿真絲堿減量工序產(chǎn)生的，主要含滌綸水解物對苯二甲酸、乙二醇等，其中對苯二甲酸含量高達75%。堿減量廢水不僅pH值高(一般>12)，而且有機物濃度高，堿減量工序排放的廢水中CODCr可高達9萬mg/L，高分子有機物及部分染料很難被生物降解，此種廢水屬高濃度難降解有機廢水。</span></p><p><span style="color: rgb(0, 102, 0); font-family: 宋體; background-color: rgb(255, 255, 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